diff --git a/compiler/src/dotty/tools/dotc/core/Definitions.scala b/compiler/src/dotty/tools/dotc/core/Definitions.scala
index 1268bdfde6ce..db0878d0d0b0 100644
--- a/compiler/src/dotty/tools/dotc/core/Definitions.scala
+++ b/compiler/src/dotty/tools/dotc/core/Definitions.scala
@@ -958,7 +958,7 @@ class Definitions {
     tpnme.Abs, tpnme.Negate, tpnme.Min, tpnme.Max, tpnme.ToString,
   )
   private val compiletimePackageBooleanTypes: Set[Name] = Set(tpnme.Not, tpnme.Xor, tpnme.And, tpnme.Or)
-  private val compiletimePackageStringTypes: Set[Name] = Set(tpnme.Plus)
+  private val compiletimePackageStringTypes: Set[Name] = Set(tpnme.Error, tpnme.Plus)
 
   final def isCompiletimeAppliedType(sym: Symbol)(implicit ctx: Context): Boolean = {
     def isOpsPackageObjectAppliedType: Boolean =
diff --git a/compiler/src/dotty/tools/dotc/core/StdNames.scala b/compiler/src/dotty/tools/dotc/core/StdNames.scala
index f4179577ad90..cdfb91dbca76 100644
--- a/compiler/src/dotty/tools/dotc/core/StdNames.scala
+++ b/compiler/src/dotty/tools/dotc/core/StdNames.scala
@@ -211,6 +211,7 @@ object StdNames {
     final val Abs: N       = "Abs"
     final val And: N       = "&&"
     final val Div: N       = "/"
+    final val Error: N     = "Error"
     final val Equals: N    = "=="
     final val Ge: N        = ">="
     final val Gt: N        = ">"
diff --git a/compiler/src/dotty/tools/dotc/core/Types.scala b/compiler/src/dotty/tools/dotc/core/Types.scala
index fefe1b5c1cd1..d27e715cc38b 100644
--- a/compiler/src/dotty/tools/dotc/core/Types.scala
+++ b/compiler/src/dotty/tools/dotc/core/Types.scala
@@ -3715,7 +3715,8 @@ object Types {
               case tpnme.Max if nArgs == 2 => constantFold2(intValue, _ max _)
               case _ => None
             } else if (owner == defn.CompiletimeOpsPackageObjectString.moduleClass) name match {
-              case tpnme.Plus if nArgs == 2 => constantFold2(stringValue, _ + _)
+              case tpnme.Error if nArgs == 1 => constantFold1(stringValue, msg => throw new TypeError(msg))
+              case tpnme.Plus  if nArgs == 2 => constantFold2(stringValue, _ + _)
               case _ => None
             } else if (owner == defn.CompiletimeOpsPackageObjectBoolean.moduleClass) name match {
               case tpnme.Not if nArgs == 1 => constantFold1(boolValue, x => !x)
diff --git a/library/src/scala/compiletime/ops/package.scala b/library/src/scala/compiletime/ops/package.scala
index d7714f63e487..34b8d86197dd 100644
--- a/library/src/scala/compiletime/ops/package.scala
+++ b/library/src/scala/compiletime/ops/package.scala
@@ -24,6 +24,23 @@ package object ops {
   }
 
   object string {
+    /** Throws a compiletime error when evaluated by the compiler. For example:
+     *
+     *  ```scala
+     *  val x: Error["My error message"] = ??? // error: My error message
+     *  ```
+     *  or
+     *  ```scala
+     *  import scala.compiletime.ops.int.>=
+     *  type Positive[X <: Int] = (X >= 0) match {
+     *    case true => X
+     *    case false => Error["Expected a positive integer"]
+     *  }
+     *  val x: Positive[-1] = -1 // error: Expected a positive integer
+     *  ```
+     */
+    type Error[Msg <: String] <: Nothing
+
     /** Concatenation of two `String` singleton types.
      *  ```scala
      *  val hello: "hello " + "world" = "hello world"
diff --git a/tests/neg/singleton-ops-error.check b/tests/neg/singleton-ops-error.check
new file mode 100644
index 000000000000..96b3911e3b63
--- /dev/null
+++ b/tests/neg/singleton-ops-error.check
@@ -0,0 +1,12 @@
+-- Error: tests/neg/singleton-ops-error.scala:18:33 --------------------------------------------------------------------
+18 |  val t1: Positive = Positive[-1](-1) // error
+   |                                 ^
+   |                                 The provided value (-1) isn't positive
+-- Error: tests/neg/singleton-ops-error.scala:20:23 --------------------------------------------------------------------
+20 |  val t3 = Positive[-1](-1) // error
+   |                       ^
+   |                       The provided value (-1) isn't positive
+-- Error: tests/neg/singleton-ops-error.scala:22:11 --------------------------------------------------------------------
+22 |  val err: Error["My error message"] = ??? // error
+   |           ^
+   |           My error message
diff --git a/tests/neg/singleton-ops-error.scala b/tests/neg/singleton-ops-error.scala
new file mode 100644
index 000000000000..ba083e519f3f
--- /dev/null
+++ b/tests/neg/singleton-ops-error.scala
@@ -0,0 +1,23 @@
+import scala.compiletime.ops.int.{ToString, >=}
+import scala.compiletime.ops.string.{+, Error}
+
+object Test {
+  type Require[Cond <: Boolean, Msg <: String] = Cond match {
+    case true => Any
+    case false => Error[Msg]
+  }
+
+  opaque type Positive = Int
+
+  object Positive {
+    type RequirePositive[T <: Int] = Require[T >= 0, "The provided value (" + ToString[T] + ") isn't positive"]
+    def apply[T <: Int](value: T)(given RequirePositive[T]): Positive = value
+  }
+
+  val t0: Positive = Positive[1](1)
+  val t1: Positive = Positive[-1](-1) // error
+  val t2 = Positive[1](1)
+  val t3 = Positive[-1](-1) // error
+
+  val err: Error["My error message"] = ??? // error
+}